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International Journal of Current Microbiology and Applied Sciences (IJCMAS)
IJCMAS is now DOI (CrossRef) registered Research Journal. The DOIs are assigned to all published IJCMAS Articles.
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National Academy of Agricultural Sciences (NAAS)
NAAS Score: *5.38 (2020)
[Effective from January 1, 2020]
For more details click here

ICV 2018: 95.39
Index Copernicus ICI Journals Master List 2018 - IJCMAS--ICV 2018: 95.39
For more details click here

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Original Research Articles

PRINT ISSN : 2319-7692
Online ISSN : 2319-7706
Issues : 12 per year
Publisher : Excellent Publishers
Email : editorijcmas@gmail.com / submit@ijcmas.com
Editor-in-chief: Dr.M.Prakash
Index Copernicus ICV 2018: 95.39
NAAS RATING 2020: 5.38

Int.J.Curr.Microbiol.App.Sci.2017.6(9): 247-254
DOI: https://doi.org/10.20546/ijcmas.2017.609.033


Synthesis and Structure of a Single-Stranded Dihelicate of Copper (II) Involving Multiring Nitrogen-Heterocyclic Ligand
Nabanita Kundu*
Dept. of Chemistry, Lady Brabourne College, P-1/2, Suhrawardy Avenue, Kolkata 700017, India
*Corresponding author
Abstract:

The single stranded-helicate Copper (II) complex [Cu2 (L) Cl4].H2O (1) containing a new biologically relevant heterocyclic bis-bidentate ligand viz. 3, 3/-dipyridine-2-yl-[1.1/]bi[imidazo [1, 5-a] pyridineyl] (L) has been prepared and characterized by single-crystal X-ray diffraction analysis. The molecule is centrosymmetric where coordination environments around Cu (II) are distorted tetrahedral (τ4 = 0.36). The Cu (II) --- Cu (II) separation is 4.808 Å. Compound in its solid state structure shows π−π noncovalent interactions as well as hydrogen bonding interactions that play dominant roles in shaping the extended structure of the molecule.


Keywords: Single stranded dihelicate compound, N- heterocyclic ligand, X-ray diffraction analysis, π−π noncovalent interactions, Hydrogen bonding
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How to cite this article:

Nabanita Kundu. 2017. Synthesis and Structure of a Single-Stranded Dihelicate of Copper (II) Involving Multiring Nitrogen-Heterocyclic LigandInt.J.Curr.Microbiol.App.Sci. 6(9): 247-254. doi: https://doi.org/10.20546/ijcmas.2017.609.033